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Salt and ice mixture – change of the freezing point

When salt is added to ice it becomes a new material with a lower freezing point. Lets call this new material "salty ice"

This means that if we have some ice at 0o C and we add some salt it will become a different material ("salty ice"). This new material may well have a freezing point of say –5 oC. If the surrounding air temperature is also 0 degrees C then our "salty ice" will start melting, at 0o C it is 5 degrees above its freezing point.

As you know when you melt something you have to add heat energy to break the bonds between the molecules and turn it into a liquid. To do this it must take in heat from its immediate surroundings (in this case the original pure ice and any liquid water that may be present) and so the surroundings cool.

This may seem like a contradiction but a similar thing happens when you put a drop of meths on your hand. The meths evaporates because it take in heat energy from your hand and so your hand cools. (Here the molecules of meths actually gain energy and move faster)

However when the salty ice takes in heat energy from its surroundings it does not rise in temperature. This only happens when ALL the solid has melted. At this point the liquid will have dropped in temperature to our example of -5 oC. Up to this point the energy goes to breaking the intermolecular bonds.

 

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© Keith Gibbs 2020