The excess pressure within a bubble
The fact that air has to be blown
into a drop of soap solution to make a bubble should suggest that the pressure within the
bubble is greater than that outside. This is in fact the case: this excess pressure creates a
force that is just balanced by the inward pull of the soap film of the bubble due to its surface
tension.

Consider a soap
bubble of radius r as shown in Figure 1. Let the external pressure be P
o and the
internal pressure P
1.
The excess pressure P within the bubble is therefore
given by :
Excess pressure = P
1 -
P
1Consider the left-hand half of the bubble. The force acting
from right to left due to the internal excess pressure can be shown to be PA, where A is the
area of a section through the centre of the bubble. If the bubble is in equilibrium this force is
balanced by a force due to surface tension acting from left to right. This force is 2x2
prT (the factor of 2 is necessary because the soap film has two sides)
where T is the coefficient of surface tension of the soap film. Therefore
2x2
prT = PA = P
pr
2 giving:

A bubble of air within a
liquid has only one liquid-air surface and the excess pressure within such a bubble is
simply:

Both these
formulae show that the excess pressure within a small bubble is greater than that within a
larger bubble.